Solivagant. \sōˈlivəgənt\
Both a noun and adjective.
To begin with the Latin, where everything begins…
The prefix:
soli-, sol-
(Latin: one, alone, only)
And the suffix:
vaga-, vag-, vago-
(Latin: wander, move around; unsettled, wandering [nerve])
Thank you, Professor Kobleske. My years of Latin still pay off.